Stabilization and strong oxidizing properties of Ag(II) in a fluorine-free solvent.
نویسندگان
چکیده
Divalent silver is stabilized in concentrated sulphuric acid and oleums. The formal redox potential of the Ag(II)/Ag(I) redox pair is markedly dependent on the Hammett acidity function and it reaches +2.90 V vs. NHE in 33% oleum thus rivalling E° for the F2/2F(-) redox pair (+2.87 V).
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عنوان ژورنال:
- Chemical communications
دوره 49 68 شماره
صفحات -
تاریخ انتشار 2013